Yes, as S2000 says, those " i " means the data observations, they can be temporal data or cross-sectional data. For example, set X variable as consumption. So Xi is the " i-th " observation of the sample you got about consumption:
X1 = 50 dollar consumption of Harrogath on August, 2015
X2 = 75 dollar consumption of S2000Magician on August, 2015
…
Xn = 62 dollar consumption of Javad05 on August, 2015
This is cross-sectional data of X variable.
Time-series data of variable X would be:
X1 = 62 dollar consumption of Javad05 on August, 2015
X2 = 70 dollar consumption of Javad05 on September, 2015
…
Xn = 128 dollar consumption of Javad05 on January, 2038
if you look to the assumption of linear regression (6)
-The variance of the error term is the same for all observations: E(ε2i)=σ2ε , i = 1, …, n.
-The error term, ε, is uncorrelated across observations. Consequently, E(εiεj) = 0 for all i not equal to j you can see that εi are not only value but random variable on their own so do I have to dwell on that or move on thank you
The outcome of the roll of a die is a random variable, but once you roll the die, it takes on a specific value.
So it goes with linear regression: the error term is a random variable, but once you run the regression with a specific data set, each random error term then takes on a specific value.